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CPID

Health effects of consumer products

Monsanto Campaign Herbicide

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Glyphosate, isopropylamine salt	038641-94-0	12.9		No
  2,4-D, isopropylamine salt	005742-17-6	20.6		No
  N-Methylpyrrolidone	000872-50-4	<7		Yes  NY-01: California Prop. 65 Chemical NY-24: U.S. EPA TSCA Chemical of Concern CA-01-California Prop. 65 Chemicals MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC  CoC List
  Surfactant(s) (unspecified)	000000-00-4	10.0-20.0		No
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Glyphosate, isopropylamine salt	038641-94-0	--	12.9	-------- ------- ---- No
  2,4-D, isopropylamine salt	005742-17-6	--	20.6	-------- ------- ---- No
  N-Methylpyrrolidone	000872-50-4	212-828-1	<7	H360, H319, H335, H315 ------- Yes
  Surfactant(s) (unspecified)	000000-00-4	--	10.0-20.0	-------- ------- ---- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      August 03, 2000

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      Warning: Keep out of reach of children. DANGER! CAUSES EYE BURNS. HARMFUL IF SWALLOWED. MAY CAUSE ALLERGIC SKIN REACTION. Do not get in eyes, on skin, or on clothing.

    • Acute health effects

      From MSDS LIKELY ROUTES OF EXPOSURE: Skin contact and inhalation EYE CONTACT: Causes pain, redness and tearing based on toxicity studies. SKIN CONTACT: No more than slightly toxic or slightly irritating based on toxicity studies. May cause allergic skin reaction based on toxicity studies. INHALATION:. No more than slightly toxic if inhaled based on toxicity studies. INGESTION: No more than slightly toxic based on toxicity studies. No significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed. Ingestion of a related formulation containing the same surfactant found in CAMPAIGN® Herbicide has been reported to produce gastrointestinal discomfort with irritation of the mouth, nausea, vomiting and diarrhea.

    • Chronic health effects

      From MSDS Surfactant The surfactant components of CAMPAIGN® Herbicide are reported to cause irritation to the eyes, skin and respiratory tract and may contribute to the irritation potential reported for this herbicide. Prolonged skin contact may cause more severe irritation and discomfort, with related local redness (erythema) and possible swelling (edema). N-Methylpyrrolidone (NMP) N-Methylpyrrolidone (NMP) is considered a mild to severe eye irritant. Human experience indicates that prolonged skin contact with NMP produces severe irritation. In addition, NMP is readily absorbed through the skin.

    • Carcinogenicity

      The manufacturer's Material Safety Data Sheet (MSDS) does not state whether the ingredients are considered carcinogens or potential carcinogens.

    • Handling information

      From MSDS Do not get in eyes, on skin or on clothing. When mixing, loading, or applying this product or repairing or cleaning equipment used with this product, wear eye protection (face shield or safety glasses), chemical-resistant gloves, long-sleeved shirt, long pants, socks and shoes. For applicators applying this product from a tractor that has a completely enclosed cab, eye protection is not required. Wash hands, face and arms with soap and water as soon as possible after mixing, loading, or applying this product. Wash hands, face and arms with soap and water before eating, smoking, or drinking. Wash hands and arms before using toilet. After work, remove all clothing and shower using soap and water. Do not reuse clothing worn during the previous day's mixing and loading or application of this product without cleaning first. Clothing must be kept and washed separately from other household laundry. Remove saturated clothing as soon as possible and shower. Persons engaged in open pouring of this product must also wear coveralls or a chemical resistant apron. Drift or runoff may adversely affect non-target plants. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Most cases of groundwater contamination involving phenoxy herbicides such as 2,4-D have been associated with mixing/loading and disposal sites. Caution should be exercised when handling 2,4-D pesticides at such sites to prevent contamination of groundwater supplies. Use of closed systems for mixing or transferring this pesticide will reduce the possibility of spills. Placement of the mixing/loading equipment on an impervious pad to contain spills will help prevent groundwater contamination.

    • Disposal information

      From MSDS Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixtures, or rinsate is a violation of Federal law and may contaminate groundwater. If these wastes cannot be disposed of according to label use instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Product which has been contaminated or is not wanted and will be discarded is classified as hazardous under the Federal Resource Conservation and Recovery Act (RCRA) and related state laws. Specific State and Federal requirements for handling and disposal will apply unless quantities are small and exemptions apply. State regulations may vary and State authorities should be consulted. Soil, water and other debris contaminated with this product may have to be treated as hazardous under RCRA depending on quantity and whether or not the waste meets the 2,4-D content criteria for hazardous waste. RCRA hazardous waste identification criteria are found in 40 CFR 261. State or Federal authorities should be contacted for appropriate handling and disposal methods. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. (See the individual container label for disposal information.)

    • First Aid

      From MSDS If In Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If on Skin: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing. As soon as soap is available, wash thoroughly with soap and water. Wash clothing before reuse. Sensitized persons should avoid further contact and reuse of contaminated clothing. Get medical attention. If Swallowed: Induce vomiting immediately as directed by Medical personnel. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTE: For additional human emergency first aid or treatment guidance, call collect, anytime, day or night (314) 694-4000.